反応 #806262

ord-fc90dcaa79f548298fe76ba67b91ec5b

反応方程式

CC(C)C(O)C(C)(C)CO
2,2,4-trimethylpentan-1,3-diol
CC(C)=CCCl
prenyl chloride
CC(C)=CCOCC(C)(C)C(O)C(C)C
1-(3-methyl-2-butenyloxy)-2,2,4-trimethylpentan-3-ol
収率 92.0%

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Treatment of 2,2,4-trimethylpentan-1,3-diol with prenyl chloride employing the alkylation reaction conditions described above provided 1-(3-methyl-2-butenyloxy)-2,2,4-trimethylpentan-3-ol in 92.0% yield (393.8 g, b.p.=82–84 C./0.8 mmHg).

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07132391B2uspto-grants-2006_11