反応 #799033

ord-2f368fd17f194917bfef0329a3c7b3e2

反応方程式

CC(C)(O)CCO
3-methylbutane-1,3-diol
N#Cc1c([N+](=O)[O-])cccc1[N+](=O)[O-]
2,6-dinitrobenzonitrile
→
CC(C)(O)CCOc1cccc([N+](=O)[O-])c1C#N
2-(3-hydroxy-3-methylbutoxy)-6-nitrobenzonitrile
収率 81.0%

反応物

CC(C)(O)CCO
3-methylbutane-1,3-diol
N#Cc1c([N+](=O)[O-])cccc1[N+](=O)[O-]
2,6-dinitrobenzonitrile

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Prepared as in Example 215c from 3-methylbutane-1,3-diol and 2,6-dinitrobenzonitrile in 81% yield. MS 251 (MH+).

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US09181276B2uspto-grants-2015_11