反応 #75424

反応方程式

acrylonitrile

tert-dodecyl mercaptan

TNPP Irganox 1076

sodium stearate

sodium bicarbonate

sodium hydroxide

potassium persulfate

→

acrylonitrile/butadiene methyl ethenyl benzene

溶媒

water

反応条件

後処理

1. 1
   その他Into a clean, dry
2. 2
   その他nitrogen-purged
3. 3
   workup.ADDITIONthree liter, four neck, round bottom flask was charged 272.7 g of polybutadiene latex (Polysar PL-662) (55% polybutadiene)
4. 4
   その他The flask was fitted with a stirrer
5. 5
   温度thermometer, reflux
6. 6
   workup.ADDITIONcondenser and 1000 ml addition funnel
7. 7
   その他A solution was prepared
8. 8
   その他was obtained
9. 9
   workup.ADDITIONThis solution was then charged into the reaction flask
10. 10
    その他was prepared
11. 11
    workup.STIRRINGWith stirring
12. 12
    その他controlled at 60° C.
13. 13
    workup.ADDITIONmonomer addition
14. 14
    温度maintained at 0.5%/min
15. 15
    workup.ADDITIONAfter all the monomer had been added
16. 16
    その他polymerization
17. 17
    workup.ALIQUOTThe latex was sampled
18. 18
    workup.ADDITIONAntioxidant was added to the latex in the form of 42 g of an 18% emulsion
19. 19
    workup.ADDITIONcontaining 2/1

実験手順

Into a clean, dry, nitrogen-purged, three liter, four neck, round bottom flask was charged 272.7 g of polybutadiene latex (Polysar PL-662) (55% polybutadiene). The flask was fitted with a stirrer, thermometer, reflux condenser and 1000 ml addition funnel. A solution was prepared by mixing 12.0 g sodium stearate, 0.9 g sodium bicarbonate, 1.5 g sodium hydroxide, 3.0 g potassium persulfate and 1322 g deionized water. The mixture was heated to 60° C. while stirring until a clear, homogeneous solution was obtained. This solution was then charged into the reaction flask to dilute the stirred polybutadiene latex. A solution containing 435.6 g of the mixture of Example 1, 164.4 g acrylonitrile and 2.7 g tert-dodecyl mercaptan was prepared and placed in the addition funnel. With stirring and the charge temperature controlled at 60° C., monomer addition was started and maintained at 0.5%/min. After all the monomer had been added, polymerization was allowed to proceed for one additional hour. The latex was sampled to determine conversion by measuring total solids content. Antioxidant was added to the latex in the form of 42 g of an 18% emulsion containing 2/1--TNPP/Irganox 1076.

出典