反応 #75023

反応方程式

Octene-1

potassium acetate

→

gamma-n-hexyl-butyrolactone

収率 61.0%

溶媒

acetic acid

反応条件

後処理

1. 1
   workup.WAITAfter a period of less than two hours

実験手順

Octene-1 in an amount of 2.24 g. and 5.1 g. of Mn2O3 (comprising two equivalents of Mn+3 based on titration value) were refluxed under nitrogen in 200 ml. glacial acetic acid containing 60 g. potassium acetate. After a period of less than two hours, gamma-n-hexyl-butyrolactone was obtained in a yield of 61%.

出典