反応 #74963

反応方程式

Hexachlorocyclopentadiene

tert-butyl-p-benzoquinone

→

6-tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione

溶媒

toluene

反応条件

後処理

1. 1
   洗浄The solid was washed with methanol
2. 2
   その他recrystallized from benzene
3. 3
   その他Yellow crystals were obtained melting at 124°-125° C.

実験手順

Hexachlorocyclopentadiene, 40 g., and 15.4 g. of tert-butyl-p-benzoquinone were dissolved in 300 ml. of toluene and refluxed for four hours. The solution solidified upon cooling to room temperature. The solid was washed with methanol and recrystallized from benzene. Yellow crystals were obtained melting at 124°-125° C.

出典