反応 #74890

ord-1a06f9ffbc2c46afaf47b657be09d7f6

反応方程式

O=[N+]([O-])c1ccc2c3c(cccc13)CC2
5-Nitroacenaphthene
O=[N+]([O-])O
nitric acid
[Sn]
tin
NN
hydrazine
c1cc2c3c(cccc3c1)CC2
acenaphthene
Nc1ccc2c3c(cccc13)CC2
5-aminoacenaphthene

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

5-Nitroacenaphthene is made by nitrating acenaphthene with nitric acid in the presence of acetic acid according to the method of Rowe and Davies, J. Chem. Soc. 117, 1346 (1920). Standard reduction methods using tin or stannous chloride in hydrochloric acid or by using Raney nickel with ethanol or hydrazine produces 5-aminoacenaphthene.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04174342uspto-grants-1979_11