反応 #74876

反応方程式

2,4-dinitrofluorobenzene

1-(2-acetamidoethyl)tetrazole-5-thiol

triethylamine

→

1-(2-acetamidoethyl)-5-(2,4-dinitrophenylthio)tetrazole

溶媒

acetone

acetone

反応条件

後処理

1. 1
   ろ過The solid material was collected by filtration
2. 2
   その他recrystallized from acetonitrile

実験手順

A solution of 9.3 g. (0.050 mol) of 2,4-dinitrofluorobenzene in 50 ml. of acetone was added to a solution of 9.35 g. (0.050 mol) of 1-(2-acetamidoethyl)tetrazole-5-thiol and 6.85 ml. (0.050 mol) of triethylamine in 100 ml. of acetone and the reaction mixture was stirred for 1 hour. The solid material was collected by filtration and recrystallized from acetonitrile to give 1-(2-acetamidoethyl)-5-(2,4-dinitrophenylthio)tetrazole, mp 197°-198° C.

出典