反応 #741715

反応方程式

α-methylbenzyl chloride

N,N-dimethylaniline

sodium hexafluoroantimonate

→

title compound

N-α-methylbenzyl-N,N-dimethylanilinium hexafluoroantimonate

溶媒

methanol

反応条件

後処理

1. 1
   その他After the reaction
2. 2
   その他the solvent was evaporated in vacuo and ether-water
3. 3
   workup.ADDITIONwas added to the residue
4. 4
   抽出to extract unreacted reactants in the etherial layer
5. 5
   ろ過filtered
6. 6
   洗浄washed
7. 7
   その他dried

実験手順

4.218 g (0.03 mol) of α-methylbenzyl chloride and 3.638 g (0.03 mol) of N,N-dimethylaniline were reacted in 40 ml of methanol at 40° C. for 3 days. After the reaction, the solvent was evaporated in vacuo and ether-water was added to the residue to extract unreacted reactants in the etherial layer. To the aqueous layer was added 7.77 g (0.03 mol) of sodium hexafluoroantimonate. The resulting crystals were suction filtered, washed and dried to give the title compound.

出典