反応 #7319

反応方程式

pentafluoroethanesulfonic anhydride

pentafluoroethanesulfonic acid

dimethyl carbonate

→

methyl pentafluoroethanesulfonate

収率 84.1%

反応条件

後処理

1. 1
   温度reflux
2. 2
   温度cooling
3. 3
   workup.STIRRINGThe solution is stirred for one hour at a temperature of 60° C. and subsequently for a further 3 hours at 110° C
4. 4
   workup.DISTILLATIONAfter distillation, 5.41 g of methyl pentafluoroethanesulfonate
5. 5
   その他are isolated (boiling range: 114–115° C., yield: 84.1%)

実験手順

5.74 g (15.0 mmol) of pentafluoroethanesulfonic anhydride and 0.31 g (1.55 mmol) of pentafluoroethanesulfonic acid are initially introduced in a 10 ml round-necked flask. 1.35 g (15.0 mmol) of dimethyl carbonate are added at room temperature with constant stirring and reflux cooling. The solution is stirred for one hour at a temperature of 60° C. and subsequently for a further 3 hours at 110° C. After distillation, 5.41 g of methyl pentafluoroethanesulfonate are isolated (boiling range: 114–115° C., yield: 84.1%).

出典