反応 #712381

反応方程式

9-Phenyl-9H,9′H-[3,3′]bicarbazolyl

4-bromo-iodobenzene

potassium carbonate

sodium bisulfite

→

9-(4-bromophenyl)-9′-phenyl-9H,9′H-[3,3′]bicarbazolyl

収率 97.2%

溶媒

toluene

orthodichlorobenzene

反応条件

後処理

1. 1
   温度heated
2. 2
   温度The mixture was cooled to 90° C.
3. 3
   workup.DISSOLUTIONdissolved
4. 4
   その他After removing the insolubles
5. 5
   ろ過by filtration
6. 6
   濃縮the filtrate was concentrated under reduced pressure
7. 7
   その他crystallized from methanol (50 ml)

実験手順

9-Phenyl-9H,9′H-[3,3′]bicarbazolyl (12.9 g), 4-bromo-iodobenzene (13.4 g), a copper powder (0.64 g), potassium carbonate (8.34 g), sodium bisulfite (0.49 g), and orthodichlorobenzene (50 ml) were added to a nitrogen-substituted reaction vessel, heated, and stirred at 170° C. for 19.5 hours. The mixture was cooled to 90° C., and dissolved after adding toluene (200 ml). After removing the insolubles by filtration, the filtrate was concentrated under reduced pressure, and crystallized from methanol (50 ml) to obtain a white powder of 9-(4-bromophenyl)-9′-phenyl-9H,9′H-[3,3′]bicarbazolyl (17.30 g; yield 97%).

出典