反応 #71011

反応方程式

4-hydroxybutylacrylate glycidylether

2-benzoyl benzoic acid

acetonitrile

2,6-di-tert-butyl-4-methylphenol

→

2-benzoyl-benzoic acid 3-(4-acryloyloxy-butoxy)-2-hydroxy-propyl ester

溶媒

dimethylacetamide

反応条件

後処理

1. 1
   温度was heated to reflux
2. 2
   温度at reflux temperature for 16 hours

実験手順

A reaction mixture containing 2-benzoyl benzoic acid (40.0 g, 0.1722 mol), acetonitrile (300 mL), dimethylacetamide (10 mL), tetrabutylammonium bromide (5.6 g, 17.22 mmol) and 2,6-di-tert-butyl-4-methylphenol (0.3 g, 1.4 mmol) was heated to reflux. At this temperature 4-hydroxybutylacrylate glycidylether (28.0 g, 140 mmol) was added and the mixture was allowed to stir at reflux temperature for 16 hours.

出典