反応 #69889

反応方程式

tetrachlorophthalic anhydride

4-chlororesorcinol

resorcinol

→

2′,4,5,6,7-pentachloro-3′,6′-dihydroxy-3H-spiro[isobenzofuran-1,9′-xanthen]-3-one

収率 82.1%

反応条件

実験手順

Treatment of tetrachlorophthalic anhydride (5 g, 17.48 mmol), 4-chlororesorcinol (2.78 g, 19.23 mmol) and resorcinol (2.12 g, 19.23 mmol) according to the procedure described in Example 1 Step 1 provided 7.24 g of 18.6% pure 2′,4,5,6,7-pentachloro-3′,6′-dihydroxy-3H-spiro[isobenzofuran-1,9′-xanthen]-3-one that was collected and taken to the next step as a mixture.

出典