反応 #67900

反応方程式

Phthalide

hydrogen

→

1,2-benzenedimethanol

溶媒

tetrahydrofuran

反応条件

後処理

1. 1
   その他equipped with a stirrer
2. 2
   その他The reaction liquid

実験手順

Phthalide (5 mmol), a ruthenium complex 1 (0.025 mmol), and tetrahydrofuran (2 mL) were charged into a 100-mL autoclave equipped with a stirrer. Then, the mixture was subjected to hydrogenation at a hydrogen pressure of 5 MPa at 100° C. for 16 hours. The reaction liquid was analyzed by gas chromatography. As a result, 1,2-benzenedimethanol was obtained at a conversion rate of 66% and a selectivity of 99% or more.

出典