反応 #674284

反応方程式

4-butoxybenzene-1,3-diamine dihydrochloride

2-[ethyl(4-nitrosophenyl)amino]ethanol

→

2-{[4-(2-amino-5-ethoxy-4-imino cyclohexa-2,5-dienylideneamino)phenyl]-ethylamino}ethanol hydrochloride

溶媒

sodium hydroxide

water

反応条件

後処理

1. 1
   その他the supernatant is removed
2. 2
   洗浄the residual gum is washed with water
3. 3
   その他The solid formed
4. 4
   ろ過is filtered off
5. 5
   その他dried

実験手順

A solution of 4-butoxybenzene-1,3-diamine dihydrochloride in 4.2 ml of 0.25N sodium hydroxide is added to a solution of 2-[ethyl(4-nitrosophenyl)amino]ethanol in 4.2 ml of water at 50° C. After 3 hours at 50° C., the supernatant is removed and the residual gum is washed with water and then taken up in isopropyl ether. The solid formed is filtered off and dried. 360 mg of 2-{[4-(2-amino-5-ethoxy-4-imino cyclohexa-2,5-dienylideneamino)phenyl]-ethylamino}ethanol hydrochloride 65 are thus obtained in the form of a black powder.

出典