反応 #668815

反応方程式

formic acid

1,8-diaminonaphthalene

ammonia

→

1H-Perimidine

溶媒

water

反応条件

後処理

1. 1
   温度the mixture is cooled to 15-20° C.
2. 2
   温度It is cooled to 10° C.
3. 3
   workup.STIRRINGsubsequently stirred at 10° C. for 1 hour
4. 4
   その他The product which is precipitated
5. 5
   その他is isolated by filtration
6. 6
   洗浄washed with water
7. 7
   その他dried in vacuo at 800 C

実験手順

95.0 g of formic acid are added to 15.8 g of 1,8-diaminonaphthalene and the mixture is stirred at reflux temperature (100° C.) for 1 hour. Then 200 ml of water are added, and the mixture is cooled to 15-20° C. and adjusted to a pH of 8.5 by addition of 25% strength by weight ammonia. It is cooled to 10° C. and subsequently stirred at 10° C. for 1 hour. The product which is precipitated is isolated by filtration, washed with water and dried in vacuo at 800 C.

出典