反応 #6669
ord-da416716b18045318a79e460f3c3b0be
反応方程式
sodium carbonate
CH3CHClCOOH
CH2═CHCH2CH2OH
sulfuric acid
→
CH3CHClCOOCH2CH2CH═CH2
反応条件
詳細条件
See reaction.notes.procedure_details.
後処理
- 1洗浄The organic layer was washed with 150 ml of water
- 2乾燥dried over magnesium sulfate
- 3ろ過subjected to filtration
- 4その他to obtain a crude liquid
- 5濃縮The crude liquid was concentrated
実験手順
CH3CHClCOOH (50 g) and CH2═CHCH2CH2OH (75 ml) were put into a flask, and 10 ml of concentrated sulfuric acid was added dropwise, followed by stirring at room temperature for 10 minutes. The reaction solution was poured into 250 ml of a saturated sodium carbonate aqueous solution. 150 ml of water and 150 ml of t-butylmethyl ether were added for liquid separation to obtain a t-butylmethyl ether layer as an organic layer. The organic layer was washed with 150 ml of water, dried over magnesium sulfate and then subjected to filtration to obtain a crude liquid. The crude liquid was concentrated to obtain CH3CHClCOOCH2CH2CH═CH2.