反応 #66435

ord-cda3a113e7984ffbbcb9d5012335d664

溶媒

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    洗浄washed with aq. NaOH and brine
  2. 2
    濃縮concentrated in vacuo

実験手順

To a chilled suspension of 3-aminobenzyl alcohol (9.24 g, 75 mmol) in THF (50 mL) was added neat acetic anhydride (8.1 mL, 86 mmol). The reaction mixture was stirred cold for 1 hr, diluted with EtOAc, washed with aq. NaOH and brine, and concentrated in vacuo to give N-[3-(hydroxymethyl)phenyl]acetamide (10.5 g, 85%).

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08524721B2uspto-grants-2013_09