反応 #661208

反応方程式

2,2′-azobis(methyl 2-methylpropionate)

glycidyl acrylate

2-hydroxyethyl methacrylate

p-acetoxystyrene

→

glycidyl acrylate 2-hydroxyethyl methacrylate p-acetoxystyrene

溶媒

methyl isobutyl ketone

heptane

反応条件

後処理

1. 1
   その他as a radical polymerization initiator, and polymerization
2. 2
   温度The reaction solution was cooled
3. 3
   その他to precipitate a polymer
4. 4
   ろ過The crystal was collected by filtration
5. 5
   workup.DISSOLUTIONdissolved in diethylene glycol dimethyl ether
6. 6
   その他were removed by distillation under reduced pressure

実験手順

Into a 500 ml-volume three-neck flask, 46.1 g (0.36 mol) of glycidyl acrylate, 15.6 g (0.12 mol) of 2-hydroxyethyl methacrylate, 19.5 g (0.12 mol) of p-acetoxystyrene and 300 ml of methyl isobutyl ketone were charged. A catalytic amount of 2,2′-azobis(methyl 2-methylpropionate) was added thereto as a radical polymerization initiator, and polymerization was allowed to proceed at 80° C. for 6 hours in a nitrogen stream. The reaction solution was cooled and then poured in a large amount of heptane to precipitate a polymer. The crystal was collected by filtration and dissolved in diethylene glycol dimethyl ether, and heptane and methyl isobutyl ketone contained in the solution were removed by distillation under reduced pressure to obtain Polymer A2-2 (glycidyl acrylate/2-hydroxyethyl methacrylate/p-acetoxystyrene) as a diethylene glycol dimethyl ether solution.

出典