反応 #65880

反応方程式

4-vinylcyclohexene

allyldichlorosilane

→

6-(3-hexenyl)-4,4-dichloro-4-sila-1-hexene

溶媒

isopropanol

反応条件

後処理

1. 1
   workup.ADDITIONwere added to the flask
2. 2
   その他the solution was further reacted for 3 hrs
3. 3
   その他the reaction
4. 4
   workup.DISTILLATIONVacuum distillation (70-73° C./0.5 torr) of the product mixture

実験手順

Using the same apparatus and procedure described in EXAMPLE 1, 37.8 g (0.35 mol) of 4-vinylcyclohexene and 60 μl of 1% chloroplatinic acid in isopropanol were added to the flask. Through the dropping funnel was added dropwise 10.0 g (0.07 mmol) of allyldichlorosilane for 30 min at 80° C. and the solution was further reacted for 3 hrs to complete the reaction. Vacuum distillation (70-73° C./0.5 torr) of the product mixture gave 13.5 g (78%) of 6-(3-hexenyl)-4,4-dichloro-4-sila-1-hexene.

出典