反応 #658770

反応方程式

9-phenylanthracene

bromosuccinimide

→

9-bromo-10-phenylanthracene

収率 89.3%

溶媒

N,N dimethylformamide

反応条件

後処理

1. 1
   その他to react for six hours
2. 2
   workup.DISTILLATIONThen, distilled water
3. 3
   workup.ADDITIONwas added
4. 4
   その他the reaction
5. 5
   ろ過the deposit was filtered
6. 6
   その他The recovered deposit was purified by column chromatography

実験手順

An amount of 13.65 (53.7 mmol) of 9-phenylanthracene was dissolved in 100 ml of N,N dimethylformamide. An amount of 10.5 g (59 mmol) of N bromosuccinimide was added and allowed to react for six hours. Then, distilled water was added to stop the reaction and the deposit was filtered. The recovered deposit was purified by column chromatography to obtain 15.97 g (48 mmol) of 9-bromo-10-phenylanthracene. The yield was 89.3%.

出典