反応 #65877

反応方程式

1-hexene

allyldichlorosilane

→

4,4-dichloro-4-sila-1 -decene

溶媒

isopropanol

反応条件

後処理

1. 1
   workup.ADDITIONwere added to the flask
2. 2
   温度while refluxing
3. 3
   その他the reaction, vacuum distillation (48°-50° C./0.5 torr)

実験手順

Using the same apparatus and procedure described in EXAMPLE 1, 59.7 g (0.71 mol) of 1-hexene and 80 μl of 1% chloroplatinic acid in isopropanol were added to the flask. Through the dropping funnel was added dropwise 10 g (0.07 mmol) of allyldichlorosilane for 30 rain while refluxing. After confirming by gas chromatography to complete the reaction, vacuum distillation (48°-50° C./0.5 torr) gave 12.5 g (79.3%) of 4,4-dichloro-4-sila-1 -decene.

出典