反応 #651861

ord-f5f58d7160c041bd84f07e4240948f92

反応方程式

CCCCCCCCOc1ccc2c(c1)cc(F)c1cc(Br)ccc12
7-bromo-9-fluoro-2-octyloxyphenanthrene
CCCCCCc1ccc(B(O)O)cc1
4-hexylphenyl-boronic acid
O=C([O-])[O-].[Na+].[Na+]
sodium carbonate
→
CCCCCCCCOc1ccc2c(c1)cc(F)c1cc(-c3ccc(CCCCCC)cc3)ccc12
9-Fluoro-7-(4-hexylphenyl)-2-octyloxyphenanthrene

反応物

CCCCCCCCOc1ccc2c(c1)cc(F)c1cc(Br)ccc12
7-bromo-9-fluoro-2-octyloxyphenanthrene
CCCCCCc1ccc(B(O)O)cc1
4-hexylphenyl-boronic acid
O=C([O-])[O-].[Na+].[Na+]
sodium carbonate

試薬

[Pd].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1
tetrakis(triphenylphosphine)palladium(O)

溶媒

CCO.Cc1ccccc1.O
toluene ethanol H2O

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

From 7-bromo-9-fluoro-2-octyloxyphenanthrene by reaction with 4-hexylphenyl-boronic acid, sodium carbonate and tetrakis(triphenylphosphine)palladium(O) in toluene/ethanol/H2O.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US06168838Auspto-grants-2001_01