反応 #645187

反応方程式

Para-aminodiphenylamine

2-undecanone

hydrogen

→

N-(1-methyldecyl)-N′-phenyl-p-phenylenediamine

反応条件

後処理

1. 1
   workup.ADDITIONwere charged to a one-liter stirred autoclave
2. 2
   その他The vessel was sealed
3. 3
   その他as indicated by the cessation of hydrogen absorption
4. 4
   温度The vessel was cooled
5. 5
   その他the contents removed
6. 6
   その他The catalyst was removed by filtration
7. 7
   その他the water was separated
8. 8
   その他The excess ketone reactant was removed
9. 9
   温度by heating in vacuo

実験手順

Para-aminodiphenylamine (184 grams, 1.00 mole), 2-undecanone (221 grams, 1.30 moles) and 6.0 grams (dry weight) of carbon supported platinum sulfide catalyst were charged to a one-liter stirred autoclave. The vessel was sealed, pressurized first with nitrogen and then with hydrogen gas, stirred, and heated to 120° C. until the reaction was completed, as indicated by the cessation of hydrogen absorption. The vessel was cooled, vented, and the contents removed. The catalyst was removed by filtration and the water was separated. The excess ketone reactant was removed by heating in vacuo.

出典