反応 #643421

ord-40e1e37604244a699cdf4239eb6881f8

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他separated into two layers

実験手順

88.2 g (0.44 mole) of phenacyl bromide and 39.1 g (0.44 mole) of tetrahydrothiophene were dissolved in 220 g of nitromethane, which was stirred for 4 hours at room temperature. 800 g of water and 400 g of diethyl ether were added to the reaction solution whereupon the mixture separated into two layers. The aqueous layer was taken out, which was an aqueous solution of the target compound, phenacyltetrahydrothiophenium bromide.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08057985B2uspto-grants-2011_11