反応 #640569

ord-af305775d42441828db19ac705114b02

反応方程式

CCOCC
diethyl ether
CSc1ccccc1
thioanisole
COS(=O)(=O)OC
dimethyl sulfate
C[S+](C)c1ccccc1.C[S+](C)c1ccccc1.O=S(=O)([O-])[O-]
dimethylphenylsulfonium sulfate

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

At room temperature, 6.2 g (0.05 mole) of thioanisole and 6.9 g (0.055 mole) of dimethyl sulfate were stirred for 12 hours. To the reaction solution were added 100 g of water and 50 ml of diethyl ether. The water layer was taken out, obtaining an aqueous solution of the desired dimethylphenylsulfonium sulfate.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08048610B2uspto-grants-2011_11