反応 #64046

ord-5cb6474f52844c2bba022377de34628a

反応方程式

CCC(=O)C1=C(O)CC(c2c(C)cccc2C)CC1=O
3-hydroxy-5-(2,6-dimethylphenyl)-2-propionylcyclohex-2-en-1-one
O=S(=O)(O)Cl
chlorosulfonic acid
CNC
dimethylamine
CCON.Cl
ethoxyamine hydrochloride
→
CCON=C(CC)C1=C(O)CC(c2c(C)ccc(S(=O)(=O)N(C)C)c2C)CC1=O
2-[1-(Ethoxyimino)propyl]-3-hydroxy-5-(2,6-dimethyl-3-dimethylsulfamoylphenyl)cyclohex-2-en-1-one

反応物

CCC(=O)C1=C(O)CC(c2c(C)cccc2C)CC1=O
3-hydroxy-5-(2,6-dimethylphenyl)-2-propionylcyclohex-2-en-1-one
O=S(=O)(O)Cl
chlorosulfonic acid
CNC
dimethylamine
CCON.Cl
ethoxyamine hydrochloride

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

2-[1-(Ethoxyimino)propyl]-3-hydroxy-5-(2,6-dimethyl-3-dimethylsulfamoylphenyl)cyclohex-2-en-1-one (5) was prepared from 3-hydroxy-5-(2,6-dimethylphenyl)-2-propionylcyclohex-2-en-1-one, chlorosulfonic acid, dimethylamine, and ethoxyamine hydrochloride following essentially the same procedure as that described in Example 5.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04767879uspto-grants-1988_08