反応 #64044

ord-b099b8f5a2e24785b4857404ef872c63

反応方程式

CCON.Cl
ethoxyamine hydrochloride
CCC(=O)C1=C(O)CC(c2c(C)cc(C)c(S(N)(=O)=O)c2C)CC1=O
3-hydroxy-5-(2,4,6-trimethyl-3-sulfamoylphenyl)-2-propionylcyclohex-2-en-one
→
CCON=C(CC)C1=C(O)CC(c2c(C)cc(C)c(S(N)(=O)=O)c2C)CC1=O
2-[1-(ethoxyimino)propyl]-3-hydroxy-5-(2,4,6-trimethyl-3-sulfamoylphenyl)cyclohex-2-en-1-one
CCON=C(CC)C1=C(O)CC(c2c(C)cc(C)c(S(N)(=O)=O)c2C)CC1=O
2-[1-(Ethoxyimino)propyl]-3-hydroxy-5-(2,4,6-trimethyl-3-sulfamoylphenyl)cyclohex-2-en-1-one

反応物

CCON.Cl
ethoxyamine hydrochloride
CCC(=O)C1=C(O)CC(c2c(C)cc(C)c(S(N)(=O)=O)c2C)CC1=O
3-hydroxy-5-(2,4,6-trimethyl-3-sulfamoylphenyl)-2-propionylcyclohex-2-en-one
—
( iv )

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Reaction of ethoxyamine hydrochloride with 3-hydroxy-5-(2,4,6-trimethyl-3-sulfamoylphenyl)-2-propionylcyclohex-2-en-one following essentially the same procedure as that described in Example 1 part (iv) gave 2-[1-(ethoxyimino)propyl]-3-hydroxy-5-(2,4,6-trimethyl-3-sulfamoylphenyl)cyclohex-2-en-1-one (12). The compound was characterized by its proton magnetic resonance spectrum which is given in Table 5, Example 37.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04767879uspto-grants-1988_08