反応 #635057

反応方程式

hexamethylene diisocyanate

dibutyltin laurate

TAKENATE

hydroquinone monomethyl ether

→

urethane acrylate

溶媒

toluene

toluene

反応条件

後処理

1. 1
   workup.ADDITIONwere mixed

実験手順

50 parts of toluene, 25 parts of hexamethylene diisocyanate subjected to isocyanurate modification (“TAKENATE D-170N”), 162.8 parts of polycaprolactone-modified hydroxyethyl acrylate (“PLACCEL FA10”, trade name, produced by Daicel Chemical Industries, Ltd.), 0.02 parts of dibutyltin laurate, and 0.02 parts of hydroquinone monomethyl ether were mixed and the mixture was maintained at 70° C. for 5 hours. Thereafter, 137.8 parts of toluene was added to obtain a urethane acrylate having a solid content of 50% by weight. The number of repetitions of a caprolactone unit per one residue of the acrylate monomer in the obtained urethane acrylate is 10.

出典