反応 #63291

反応方程式

iodobenzene

diphenylamine

potassium hydroxide

→

triphenylamine

収率 82.0%

反応条件

後処理

1. 1
   workup.ADDITIONfollowing charge
2. 2
   その他The above-identified product was obtained as colorless crystals

実験手順

The same equipment and conditions as in example I were employed with the following charge: 20.4 grams (0.1 mole) iodobenzene, 27.4 grams (0.15 mole) diphenylamine, 16.8 grams (0.3 mole) potassium hydroxide flakes, 15.0 grams of copper powder and 30.0 milliliters of Soltrol® 170. The above-identified product was obtained as colorless crystals having a melting point of 125°-126° C. Yield 82%.

出典