反応 #6300

ord-c752070c8b524cd1886a9e0e3e0ee605

反応方程式

O=S(=O)(c1ccc(CBr)cc1)C(F)(F)F
4-triflyl-alpha-bromotoluene
c1ccc(P(c2ccccc2)c2ccccc2)cc1
triphenylphosphine
O=S(=O)(c1ccc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1)C(F)(F)F.[Br-]
4-Triflylbenzyltriphenylphosphonium bromide

溶媒

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    温度at reflux for 19 hours

実験手順

A solution of 30.3 g (0.1 mole) of 4-triflyl-alpha-bromotoluene and 28.8 g (0.1 mole) of triphenylphosphine in xylene is heated at reflux for 19 hours. 4-Triflylbenzyltriphenylphosphonium bromide is then isolated by filtration, washed with additional portions of xylene, and dried.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05247042uspto-grants-1993_09