反応 #617366

反応方程式

1,6-diphenylpyrene

N-bromosuccinimide

→

3-bromo-1,6-diphenylpyrene

溶媒

DMF

反応条件

後処理

1. 1
   その他to react at 60° C. for 2 days
2. 2
   温度After cooling
3. 3
   ろ過the reaction solution was filtered
4. 4
   その他solids obtained
5. 5
   洗浄were washed with clean water, methanol and clean water, and solids
6. 6
   その他obtained
7. 7
   乾燥were dried under a reduced pressure, whereby white solids of 3-bromo-1,6-diphenylpyrene (8.60 g)
8. 8
   その他were obtained

実験手順

Under a flow of argon, 11.8 g of 1,6-diphenylpyrene, 5.93 g of N-bromosuccinimide and DMF were placed into a flask. The resulting mixture was allowed to react at 60° C. for 2 days. After cooling, the reaction solution was filtered, and solids obtained were washed with clean water, methanol and clean water, and solids obtained were dried under a reduced pressure, whereby white solids of 3-bromo-1,6-diphenylpyrene (8.60 g) were obtained.

出典