反応 #6161

ord-0de16def84324b30a9beac0de74809f8

反応方程式

CCCCC/C=C\C/C=C\CCCCCCCC(O)CC1OC(=O)C1CC
3-ethyl-4-[(10Z,13Z)-2-hydroxy-10,13-nonadecadienyl)-2-oxetanone
CC(C)C[C@@H](C(=O)O)N(C)C=O
N-formyl-N-methyl-L-leucine
→
C=CCC[C@@H](C[C@@H]1OC(=O)[C@H]1CCCCCCCCCC)OC(=O)[C@H](CC(C)C)NC=O
N-formyl-L-leucine (S)-1-[[(2S,3S)-3-decyl-4-oxo-2-oxetanyl]methyl]-4-pentenyl ester

反応物

CCCCC/C=C\C/C=C\CCCCCCCC(O)CC1OC(=O)C1CC
3-ethyl-4-[(10Z,13Z)-2-hydroxy-10,13-nonadecadienyl)-2-oxetanone
CC(C)C[C@@H](C(=O)O)N(C)C=O
N-formyl-N-methyl-L-leucine

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他there was obtained

実験手順

by esterifying 3-ethyl-4-[(10Z,13Z)-2-hydroxy-10,13-nonadecadienyl)-2-oxetanone with N-formyl-N-methyl-L-leucine there was obtained

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05246960uspto-grants-1993_09