反応 #6158

ord-f2832b5fb09b4e59ad1cd227ee44f57d

反応方程式

C=CCC[C@@H](O)C[C@@H]1OC(=O)[C@H]1CCCCCC
(S)-3-hexyl-(S)-4-[(R)-2-hydroxy-5-hexenyl)-2-oxetanone
CC(C)C[C@H](NC=O)C(=O)O
N-formyl-L-leucine
→
C=CCCC(C[C@@H]1OC(=O)[C@H]1CCCCCC)OC(=O)[C@H](CC(C)C)NC=O
N-formyl-L-leucine 1-[(trans-3-hexyl-4-oxo-2-oxetanyl)methyl]-4-pentenyl ester

反応物

C=CCC[C@@H](O)C[C@@H]1OC(=O)[C@H]1CCCCCC
(S)-3-hexyl-(S)-4-[(R)-2-hydroxy-5-hexenyl)-2-oxetanone
CC(C)C[C@H](NC=O)C(=O)O
N-formyl-L-leucine

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他there was obtained

実験手順

by esterifying (S)-3-hexyl-(S)-4-[(R)-2-hydroxy-5-hexenyl)-2-oxetanone with N-formyl-L-leucine there was obtained

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05246960uspto-grants-1993_09