反応 #60323

ord-4fb961fd634446639aca2f5016437d7d

反応方程式

O=C1C=CC(=O)O1
maleic anhydride
CC1(C)CCCC(C)(C)N1[O]
TEMPO
CC(C)(C#N)N=NC(C)(C)C#N
vazo 64
O=C1C=CC(=O)O1
maleic anhydride
→
C=Cc1ccccc1
styrene
C=CC(=O)OCCCC
butylacrylate

反応物

O=C1C=CC(=O)O1
maleic anhydride
CC1(C)CCCC(C)(C)N1[O]
TEMPO
CC(C)(C#N)N=NC(C)(C)C#N
vazo 64
O=C1C=CC(=O)O1
maleic anhydride

試薬

なし

溶媒

C=CC(=O)OCCCC.C=Cc1ccccc1
styrene butylacrylate

反応条件

温度
135°CELSIUS
詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他had been deoxygenated
  2. 2
    workup.ADDITIONThe addition
  3. 3
    温度cooled

実験手順

Incorporation of maleic anhydride into an emulsion aggregation particle at the bulk polymerization step. A stock solution of styrene (390 mL) and butylacrylate (110 ml) was prepared and to 400 ml was added TEMPO (3.12 g, 0.02 mole) and vazo 64 initiator (2.0 g, 0.0125 mole). This was heated tinder a nitrogen atmosphere to 135° C. (bath temperature) and then added to it dropwise a solution of maleic anhydride (9.8 g) in 100 mL of the styrene/butylacrylate stock solution that had been deoxygenated using nitrogen. The addition was done over a 30 minute period after which it was stirred for 5 more minutes and then cooled to afford a poly(styrene/maleic anhydride-b-styrene/butylacrylate) (Mn=4,990 with PD=1.23) solution in styrene/butylacrylate monomer.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07426074B2uspto-grants-2008_09