反応 #60231

反応方程式

N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide

potassium hydroxide

diethylbenzene

water

→

N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine

収率 85.5%

溶媒

hexane

反応条件

後処理

1. 1
   workup.ADDITIONCharged
2. 2
   温度refluxed for 3 days
3. 3
   その他the reaction
4. 4
   workup.WAITthe mixture was left
5. 5
   温度cooling down
6. 6
   ろ過The brown solid matter deposited was filtered off
7. 7
   その他dried under reduced pressure

実験手順

Charged were N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]acetamide 82.0 g, a 50% potassium hydroxide aqueous solution 39 g and diethylbenzene 100 ml, and the mixture was heated and refluxed for 3 days. After finishing the reaction, the mixture was left cooling down, and water 100 ml and hexane 500 ml were added thereto. The brown solid matter deposited was filtered off and dried under reduced pressure to obtain 67 g of N,N-bis[4″-(N-phenyl-1-naphthylamino)-p-terphenyl-4-yl]amine.

出典