反応 #60214

ord-c35c1b2444a44bd4a73c55c53dcc2698

反応方程式

CN(C)CCN(CCNc1ccc([N+](=O)[O-])cn1)S(=O)(=O)c1ccccc1[N+](=O)[O-]
[2-(dimethylamino)ethyl]{2-[(5-nitro(2-pyridyl))amino]ethyl}[(2-nitrophenyl)sulfonyl]amine
OCCN1CCOCC1
4-(2-hydroxyethyl)morpholine
→
O=[N+]([O-])c1ccc(NCCN(CCN2CCOCC2)S(=O)(=O)c2ccccc2[N+](=O)[O-])nc1
(2-morpholin-4-ylethyl){2-[(5-nitro(2-pyridyl))amino]ethyl}[(2-nitrophenyl)sulfonyl]amine

反応物

CN(C)CCN(CCNc1ccc([N+](=O)[O-])cn1)S(=O)(=O)c1ccccc1[N+](=O)[O-]
[2-(dimethylamino)ethyl]{2-[(5-nitro(2-pyridyl))amino]ethyl}[(2-nitrophenyl)sulfonyl]amine
OCCN1CCOCC1
4-(2-hydroxyethyl)morpholine

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Made using the same procedure as for polymer-bound [2-(dimethylamino)ethyl]{2-[(5-nitro(2-pyridyl))amino]ethyl}[(2-nitrophenyl)sulfonyl]amine except that 4-(2-hydroxyethyl)morpholine (5.1 mL, 42 mmol) was used.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07425557B2uspto-grants-2008_09