反応 #586084

反応方程式

1-Butyl-3-methylimidazolium chloride

potassium 1,1,2-trifluoro-2-(trifluoromethoxy)ethanesulfonate

→

product

収率 67.8%

1-butyl-3-methylimidazolium 1,1,2-trifluoro-2-(trifluoromethoxy)ethanesulfonate

収率 67.8%

溶媒

water

water

反応条件

後処理

1. 1
   その他were combined at room temperature
2. 2
   その他to give a biphasic mixture with the desired ionic liquid as the bottom phase
3. 3
   その他The layers were separated
4. 4
   抽出the aqueous phase was extracted with 2×50 ml portions of methylene chloride
5. 5
   乾燥The combined organic layers were dried over magnesium sulfate
6. 6
   濃縮concentrated in vacuo
7. 7
   その他The colorless oil product was dried at for 4 hr at 5 Pa and 25 degrees C

実験手順

1-Butyl-3-methylimidazolium chloride (Bmim-Cl, 10.0 g) and deionized water (15 ml) were combined at room temperature in a 200 ml flask. At room temperature in a separate 200 ml flask, potassium 1,1,2-trifluoro-2-(trifluoromethoxy)ethanesulfonate (TTES-K, 16.4 g) was dissolved in deionized water (90 ml). These two solutions were combined at room temperature and allowed to stir magnetically for 30 min. under positive nitrogen pressure to give a biphasic mixture with the desired ionic liquid as the bottom phase. The layers were separated, and the aqueous phase was extracted with 2×50 ml portions of methylene chloride. The combined organic layers were dried over magnesium sulfate and concentrated in vacuo. The colorless oil product was dried at for 4 hr at 5 Pa and 25 degrees C. to afford 15.0 g of product.

出典