反応 #57776

ord-094995bb8405496da2908e4229898680

反応方程式

→

$C/C(=C\COP(=O)([O-])OP(=O)([O-])[O-])CCC[C@H](C)CCC[C@H](C)CCCC(C)C$

Phytyl pyrophosphate

$C/C(=C\Cc1cc(O)cc(C)c1O)CCC[C@H](C)CCC[C@H](C)CCCC(C)C$

2-methyl-6-phytylquinol

$C/C(=C\Cc1cc(O)c(C)c(C)c1O)CCC[C@H](C)CCC[C@H](C)CCCC(C)C$

2,3-dimethyl-5-phytylquinol

反応物

試薬

なし

反応条件

詳細条件

See reaction.notes.procedure_details.

実験手順

Homogentisic acid in 0.1% H3PO4 (specific radioactivity 40 Ci/mmol). Phytyl pyrophosphate was synthesized as described by Joo, et al. (1973) Can J. Biochem. 51:1527. 2-methyl-6-phytylquinol and 2,3-dimethyl-5-phytylquinol were synthesized as described by Soll, et al. (1980) Phytochemistry 19:215. Homogentisic acid, α, β, δ, and γ-tocopherol, and tocol, were purchased commercially.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07420101B2uspto-grants-2008_09