反応 #565303

反応方程式

1,4-bis(hydroxyethyl)terephthalate

ethyl phosphorodichloridate

→

BHET EOP

溶媒

methylene chloride

methylene chloride

反応条件

後処理

1. 1
   その他equipped with a funnel
2. 2
   workup.ADDITIONAfter addition
3. 3
   workup.STIRRINGthe mixture was stirred at room temperature for four hours

実験手順

Under an argon stream, 10 g of 1,4-bis(hydroxyethyl)terephthalate (BHET), 9.61 g of 4-dimethylaminopyridine (DMAP), and 70 mL of methylene chloride were placed in a 250 mL flask equipped with a funnel. The solution in the flask was cooled down to −40° C. with stirring, and a solution of 5.13 g of ethyl phosphorodichloridate (EOP) (distilled before use) in 20 mL of methylene chloride was added dropwise through the funnel. After addition was complete, the mixture was stirred at room temperature for four hours to form the homopolymer BHET-EOP.

出典