反応 #56369

反応方程式

tris(2-chloroethyl)phosphate

dimethyl methylphosphonate

methylchloride

ethylene oxide

→

Tris(2-chloroethyl)Phosphate Dimethyl Methylphosphonate

溶媒

methanol

反応条件

後処理

1. 1
   workup.ADDITIONA mixture of 571 g
2. 2
   その他26 hours
3. 3
   温度The product was then heated at 95° with 28.2 g

実験手順

A mixture of 571 g. of tris(2-chloroethyl)phosphate and 531 g. of dimethyl methylphosphonate was heated at 181°-197° C. until 287.5 of methylchloride was evolved; this required 26 hours. The product was then heated at 95° with 28.2 g. of methanol, and finally treated with ethylene oxide at 90°-100° until substantially neutral. The product was useful as a flame retardant at 5-10 phr. in a styrenated polyester.

出典