反応 #56354

反応方程式

ethyl acrylate

sodium hydroxide

potassium hydroxide

butyl acrylate

monoethyl fumarate

→

Ethyl Acrylate Butyl Acrylate Monoethyl Fumarate

溶媒

chloroform

反応条件

後処理

1. 1
   洗浄Coagulated polymer was washed
2. 2
   workup.DISSOLUTIONtwice dissolved in acetone
3. 3
   その他reprecipitated in water in a blender
4. 4
   その他air-dried
5. 5
   その他vacuum-oven dried 3.5 hrs
6. 6
   その他at 72° C., and finally mill-dried at about 130° C
7. 7
   その他The terpolymer produced

実験手順

Coagulated polymer was washed by chopping in a blender with water, twice dissolved in acetone and reprecipitated in water in a blender, then air-dried, vacuum-oven dried 3.5 hrs. at 72° C., and finally mill-dried at about 130° C. Yield: 254 g. The terpolymer produced had an inherent viscosity (chloroform, 30° C.) of 1.51 deciliters/gram and an acid content of 0.24 meq./gram (titration with aqueous sodium hydroxide), or 0.23 meq./gram (titration with alcoholic potassium hydroxide). The terpolymer had 3.3 percent monoethyl fumarate; the remainder was believed to be about equally divided between ethyl acrylate and butyl acrylate.

出典