反応 #56350

反応方程式

ethyl acrylate

boron trifluoride

allyl acrylate

azobis(isobutyronitrile)

ethylene

ethylene

maleic anhydride

→

Ethylene/Ethyl Acrylate Allyl Acrylate Maleic Anhydride

溶媒

methylene chloride

acetone

反応条件

後処理

1. 1
   workup.ADDITIONwas charged under nitrogen with 4000 ml
2. 2
   その他It was then sealed
3. 3
   その他The subsequent copolymerization at 25° C.
4. 4
   その他about two hours
5. 5
   その他The reaction was quenched by addition of one liter of diethyl ether
6. 6
   その他Volatiles were removed by steam-stripping in a well-ventilated hood
7. 7
   その他The terpolymer thereby obtained
8. 8
   その他precipitated in water in a blender
9. 9
   その他oven-dried

実験手順

A 7.57-liter stirred autoclave was charged under nitrogen with 4000 ml. of methylene chloride, 400 grams of ethyl acrylate, 20 grams of maleic anhydride, 1.2 grams of allyl acrylate, and 1.0 gram of azobis(isobutyronitrile). It was then sealed, charged with 300 grams of boron trifluoride, and pressured to 21 kg./sq. cm. with ethylene. The subsequent copolymerization at 25° C. was continued until pressure measurement indicated that ethylene uptake had ceased (about two hours later). The reaction was quenched by addition of one liter of diethyl ether. Volatiles were removed by steam-stripping in a well-ventilated hood. The terpolymer thereby obtained was dissolved in acetone, precipitated in water in a blender, and oven-dried. Yield: 415 grams.

出典