反応 #558880

ord-4f75fd2ca6b24187b86c979287659b75

反応方程式

COC(C)(C)CCO
3-methoxy-3-methylbutan-1-ol
N#Cc1c([N+](=O)[O-])cccc1[N+](=O)[O-]
2,6-dinitrobenzonitrile
→
COC(C)(C)CCOc1cccc([N+](=O)[O-])c1C#N
2-(3-methoxy-3-methylbutoxy)-6-nitrobenzonitrile
収率 52.0%

反応物

COC(C)(C)CCO
3-methoxy-3-methylbutan-1-ol
N#Cc1c([N+](=O)[O-])cccc1[N+](=O)[O-]
2,6-dinitrobenzonitrile

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Prepared as in Example 215c from 3-methoxy-3-methylbutan-1-ol and 2,6-dinitrobenzonitrile in 52% yield. MS 265 (MH+).

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08633186B2uspto-grants-2014_01