反応 #554596

反応方程式

potassium carbonate

N,N-bis(4-bromophenyl)amine

phenyl boronic acid

→

N,N-di(4-biphenylyl)amine

収率 143.8%

溶媒

ethylene glycol dimethyl ether

反応条件

後処理

1. 1
   その他After completion of reaction
2. 2
   ろ過the reaction mixture is filtrated
3. 3
   その他the obtained solid is recrystallized with chloroform and hexane

実験手順

In a nitrogen atmosphere, an ethylene glycol dimethyl ether (20 mL) solution containing 9.5 g (29 mmol) of N,N-bis(4-bromophenyl)amine, 7.9 g (65 mmol) of phenyl boronic acid, 0.15 g (0.646 mmol) of palladium acetate, and 1.4 g (4.5 mmol) of tris(o-thryl)phosphine, to which 95 mL of a potassium carbonate solution (2.0 mol/L) is added, is rectified at 90° C. for seven hours. After completion of reaction, the reaction mixture is filtrated, and the obtained solid is recrystallized with chloroform and hexane to obtain 6.7 g (yield: 72%) of N,N-di(4-biphenylyl)amine which is an object as a white powdered solid.

出典