反応 #552472

ord-dde0a09e19d9453eab1603b6f353fd0d

反応方程式

CC(C)=CCCC(C)CC(O)C=C[C@H]1C(O)CC2CC(=CCCCC(=O)O)C[C@@H]21
6,9-methylene-11,15-dihydroxy-17-methyl-20-isopropylideneprost-5,13-dienoic acid
C1CCCC(C2CCCCCCC2)CCC1
bicyclooctane
→
CC(C)=CCCCCC(O)C=C[C@H]1C(O)CC2CC(=CCCCC(=O)O)C[C@@H]21
6,9-methylene-11,15-dihydroxy-20-isopropylideneprost-5,13-dienoic acid

反応物

CC(C)=CCCC(C)CC(O)C=C[C@H]1C(O)CC2CC(=CCCCC(=O)O)C[C@@H]21
6,9-methylene-11,15-dihydroxy-17-methyl-20-isopropylideneprost-5,13-dienoic acid
—
7-(4-carboxybutylidene)-3-hydroxy-2-(3-hydroxy-5,9-dimethyl-1,8-decadienyl)
C1CCCC(C2CCCCCCC2)CCC1
bicyclooctane

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

6,9-methylene-11,15-dihydroxy-17-methyl-20-isopropylideneprost-5,13-dienoic acid {otherwise known as 7-(4-carboxybutylidene)-3-hydroxy-2-(3-hydroxy-5,9-dimethyl-1,8-decadienyl)-[3.3.0]-bicyclooctane};

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05153003uspto-grants-1992_10