反応 #551655

反応方程式

n-butyl methacrylate

n-butyl acrylate

acrylic acid

t-butyl perbenzoate

isobutyl methacrylate

t-butyl perbenzoate

→

iBMA

溶媒

butyl Cellosolve

butyl Cellosolve

isopropanol

butyl Cellosolve

反応条件

後処理

1. 1
   workup.ADDITIONa monomer mix
2. 2
   workup.ADDITIONare added to the 150° C. solvent over three hours at a constant rate
3. 3
   その他Reaction temperature
4. 4
   workup.ADDITIONafter the addition of an initiator chaser solution

実験手順

One hundred twenty-five parts of butyl Cellosolve is heated to 150° C. and a monomer mix consisting of 200 parts of isobutyl methacrylate, 137.5 parts of n-butyl methacrylate, 50 parts of n-butyl acrylate, 62.5 parts of acrylic acid and 50 parts of methacryloxyethyl esters of linseed oil fatty acids and an initiator solution consisting of 1.5 parts of t-butyl perbenzoate dissolved in 10 parts of butyl Cellosolve are added to the 150° C. solvent over three hours at a constant rate. Reaction temperature is held at 150±2° C. throughout the gradual additions and for 15 minutes after the addition of an initiator chaser solution consisting of 3 parts of t-butyl perbenzoate dissolved in 10 parts of butyl Cellosolve. The polymer solution is then cooled to 100° C. and diluted with 174 parts of isopropanol.

出典