反応 #54853

ord-12d59998ab8e47de8c6a3d918ace2533

反応方程式

C=CCOC(=O)c1cccc(C(=O)OCC=C)c1
diallyl isophthalate
C=CCOC(=O)/C=C\C(=O)OCC=C
diallyl maleate
C=CCOC(=O)CCCCC(=O)OCC=C
diallyl adipate
C=CCOC(=O)c1cc(C(=O)OCC=C)cc(C(=O)OCC=C)c1
triallyl trimesate
→
O=C([O-])CCC(=O)OC(C1CC=CCC1)C1CC=CCC1
di(4-cyclohexenyl)methyl succinate
収率 72.0%
C=CCCCCCCCCC(=O)OCCOCCO
diethylene glycol undecylenate
収率 59.6%

反応物

C=CCOC(=O)c1cccc(C(=O)OCC=C)c1
diallyl isophthalate
C=CCOC(=O)/C=C\C(=O)OCC=C
diallyl maleate
C=CCOC(=O)CCCCC(=O)OCC=C
diallyl adipate
C=CCOC(=O)c1cc(C(=O)OCC=C)cc(C(=O)OCC=C)c1
triallyl trimesate

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Other unsaturated esters which were reacted in a mole ratio of 2 MCP to 1 of ester to form adducts with 1-mercapto-3-chloro-2-propanol are diallyl isophthalate (at 100% reacted under 3 megarads radiation), diallyl maleate, diallyl adipate, di(4-cyclohexenyl)methyl succinate (10 hours exposure to ultraviolet light, 72% yield of brown liquid), diethylene glycol undecylenate (about 10 hours U.V. radiation. 59.6% yield of brown liquid), triallyl trimesate, ##STR19##

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04150237uspto-grants-1979_04