反応 #54666

反応方程式

p-menth-3-oyl chloride

glycine propyl ester hydrochloride

sodium bicarbonate

→

N-p-Menth-3-oylglycine n-propyl ester

反応条件

後処理

1. 1
   workup.DISTILLATIONThe crude product was distilled b.p. 170°/0.1 mm
2. 2
   workup.DISTILLATION(After distillation the product

実験手順

Following the procedure of Example 2 p-menth-3-oyl chloride (2.0 g., 0.01 moles), was reacted with glycine propyl ester hydrochloride (1.5 g., 0.01 moles) and sodium bicarbonate (1.6 g., 0.02 moles). The crude product was distilled b.p. 170°/0.1 mm. (After distillation the product rapidly solidifies). (Found, C: 68.2; H: 1016; N: 5.0. C16H29NO3 requires, C: 67.8; H: 10.6; N: 4.9.)

出典