反応 #54447

ord-4b0992e459a24daaa1b21148f6ab2d51

反応方程式

CCCCCCCCCCCCCCCCCC(=O)Cl
stearoyl chloride
ClCl
chlorine
O=S(=O)(O)Cl
ClSO3H
N#CC(C#N)=c1ccc(=C(C#N)C#N)cc1
TCNQ
→
CCCCCCCCCCCCCCCCC(Cl)C(=O)Cl
2-chlorostearoyl chloride

反応物

CCCCCCCCCCCCCCCCCC(=O)Cl
stearoyl chloride
ClCl
chlorine
O=S(=O)(O)Cl
ClSO3H
N#CC(C#N)=c1ccc(=C(C#N)C#N)cc1
TCNQ

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    workup.DISTILLATIONThe product is distilled

実験手順

Following the procedure of Example I, stearoyl chloride is reacted with chlorine in the presence of ClSO3H and TCNQ. The product is distilled to provide substantially pure 2-chlorostearoyl chloride.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04148811uspto-grants-1979_04