反応 #543540

反応方程式

water

phthalimide

potassium

1-bromo-4-methyl-3-pentene

→

4-Methyl-1-(phthalimido)-3-pentene

溶媒

dimethylformamide

反応条件

後処理

1. 1
   ろ過the precipitated solid was filtered
2. 2
   洗浄washed with water
3. 3
   その他the solid was dried under vacuum

実験手順

To a suspension of phthalimide, potassium derivative (11.5 g, 0.062 mol) in dry dimethylformamide (60 mL) was added 1-bromo-4-methyl-3-pentene (10.0 g, 0.061 mol) and the suspension was stirred under N2 at 90° C. for 4 h. The reaction mixture was poured into water (300 mL) and the precipitated solid was filtered and washed with water and the solid was dried under vacuum. Yield: 12.8 g (91%). mp 95-97° C. MS: (M+H)+=229.9.

出典